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Monoethanolamine_MSDS_2013_EN

Page 1 / 10

Safety data sheet according to Regulation EC No № 1907/2006

Date/ revised: 05.09.2013

Product: Monoethanolamine

Version: 3.0 / EN

SAFETY DATA SHEET

1. IDENTIFICATION OF PRODUCT AND COMPANY

1.1. Identification of the product:

Reach Registration number:

EC number:

EC name:

CAS number:

CAS name:

IUPAC name:

Molecular formula:

Molecular weight:

Acronym:

Structural formula:

Monoethanolamine

▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть

▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть

2-aminoethanol

▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть

Ethanol, 2-amino2-aminoethanol

C2H7NO

61.0831

MEA

1.2. Use of the product:

IU number

1

2

3

6

7

8

9

10

11

12

13

14

17

4

6

8

10

11

12

14

5

15

16

18

19

Identified Use (IU) name

Uses by workers in industrial settings

Manufacturing of MEA

Formulation of products containing MEA

Industrial use resulting in manufacture of another substance

Processing aid for paper, ile, leather

Gas/water treatment with MEA

Use of MEA in metal working fluids

Use of MEA in electroplating

Use of MEA in detergents, cleaners and ink removers

Use of MEA as additive in plastic, e.g. rubber

Use of MEA as a laboratory chemical

Use of MEA as additive in fuel

Use of fuel

Use of MEA in wood protection formulations

Uses by professional workers

Use as additive in concrete and cement

Processing aid for paper, ile, leather

Use of MEA in metal working fluids

Use of MEA in detergents, cleaners and ink removers

Use of MEA as additive in plastic, e.g. rubber

Use of MEA as a laboratory chemical

Use of fuel

Uses by consumers

Use of concrete and cement

Use of fuel

Use of MEA in detergents and cleaners

Use of MEA in wood protection formulations

Use of MEA in personal care products

Sector of use (SU)

1.3. Identification of the company:

Limited liability company Sintez OKA

Company:

Address:

606000, Russian Federation, Nizhny Novgorod region, Dzerzhinsk ,

East industrial area Сhimmash, 7th km of East road, building 547.

8,9

3,10

8,9

3,22

3,23

3,22

3,16,22

3,22

3,22

3,22

3,8

3,22

3

22

3,22

3,22

3,22

3,22

3,22

3,22

19,21

21

21

21

10,21

Page 2 / 10

Safety data sheet according to Regulation EC No № 1907/2006

Date/ revised: 05.09.2013

Product: Monoethanolamine

Version: 3.0 / EN

1.4. Emergency Contact:

(▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть:30am – 4:15pm

(▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открытьround-the-clock

Fax: (▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть

1.5. Person responsible for placement of the product in the market within the European Community:

Independent Petroleum Distribution SA

Andrey Bachev

118, Drève Richelle postal code : 1410, Waterloo , Belgium

Phone: +▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть

+▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть

Fax: +▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть

mail to: ▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть

2. HAZARDS IDENTIFICATION

2.1 Classification of the substance:

2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP/GHS]

Hazard classes and Hazard categories

Acute tox.: Cat. 4 (Inhalation)

Acute tox.: Cat. 4 (dermal)

Acute toxicity: Cat. 4 (oral)

Skin corr./irr.: Cat. 1B

Specific target organ toxicity - single: Cat. 3

(Inhalation)

Aquatic Chronic 3

Hazard Statements

H332: Harmful if inhaled.

H312: Harmful in contact with skin.

H302: Harmful if swallowed.

H314: Causes severe skin burns and eye damage.

H335: May cause respiratory irritation.

H412: Harmful to aquatic life with long lasting

effects.

2.1.2 Classification according to 67/548/EEC or 1999/45/EC

Xn; R20/21/22 Harmful; Harmful by inhalation, in contact with skin and if swallowed.

C; R34 Corrosive; Causes burns.

2.2 Label elements

2.2.1 Labelling according to Regulation (EC) No 1272/2008 [CLP/GHS]

Product identifier:

Substances: Monoethanolamine.

Index №:▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть0-8

Hazard pictograms:

Signal word: Danger.

Hazard statements:

H332: Harmful if inhaled.

H312: Harmful in contact with skin.

H302: Harmful if swallowed.

H314: Causes severe skin burns and eye damage.

Н335: May cause respiratory irritation.

H412: Harmful to aquatic life with long lasting effects.

Precautionary Statements (Prevention):

P202: Do not handle until all safety precautions have been read and understood.

Р260: Do not breathe dust/gas/mist/vapours.

Р264: Wash with plenty of water and soap thoroughly after handling.

Р270: Do no eat, drink or smoke when using this product.

Page 3 / 10

Safety data sheet according to Regulation EC No № 1907/2006

Date/ revised: 05.09.2013

Product: Monoethanolamine

Version: 3.0 / EN

Р271: Use only outdoors or in a well-ventilated area.

Р273: Avoid release to the environment.

P281: Use personal protective equipment as required.

P285: In case of inadequate ventilation wear respiratory protection.

Precautionary Statements (Response):

P301 + P330 + Р331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin

with water/shower.

P304 + Р340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305 + P351 + Р338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present

and easy to do. Continue rinsing.

P308 + P313: IF exposed or concerned: Get medical advice/attention.

P363: Wash contaminated clothing before reuse.

Precautionary Statements (storage):

Р403 + Р233: Store in a well-ventilated place. Keep container tightly closed.

Р405: Store locked up.

Precautionary Statements (Disposal):

P501: Dispose of contents/container to hazardous or special waste collection point.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Name

CAS №

EC №

Index №

Monoethanolamine

(MEA)

▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть

▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть

Diethanolamine

(DEA)

▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть

Water

▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть

Reach

Registration

number

Mass

concent,

%

▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть

▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть8-0009

≥ 97

▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть

▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть

▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть8-0008

≤ 2

▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть

—

—

≤ 2

Classification according

67/548/

Regulation (EC) No

EEC

1272/2008 [CLP]

Acute tox.: Cat. 4

H332:

(Inhalation)

Acute tox.: Cat. 4

H312:

(dermal)

Acute toxicity: Cat.

C;

H302:

R20/21/ 4 (oral)

22;

Skin corr./irr.: Cat.

H314:

R34

1B

STOT single: Cat.3

(irr. to respiratory

H335:

syst.)

Aquatic Chronic 3

H412:

Acute toxicity: Cat.

H302:

4 (oral)

Xi ,

Skin corrosion/

Xn,

H315:

irritation: Cat.2

R 22,

Serious eye damage

R 38,

/ irritation eye:Cat.1 H318:

R 41,

H373.

R 48/22 STOT RE 2

Aquatic Chronic 3

H412:

—

—

—

Hazard symbols deciphering is given in section 16.

4. FIRST-AID MEASURES

4.1 Description of first aid measures

4.1.1 General informations:

Immediately remove contaminated clothing. If danger of loss of consciousness, place patient in recovery position and

transport accordingly. Apply artificial respiration if necessary.

Keep patient calm, remove to fresh air, seek medical attention. Immediately inhale

4.1.2 Following inhaled:

corticosteroid.

4.1.3 Following skin contact: Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a

skin specialist.

Immediately wash affected eyes for at least 15 minutes under running water with

4.1.4 Following eye contact:

eyelids held open, consult an eye specialist.

Page 4 / 10

Safety data sheet according to Regulation EC No № 1907/2006

Date/ revised: 05.09.2013

Product: Monoethanolamine

Version: 3.0 / EN

Rinse mouth immediately and then drink plenty of water, seek medical attention.

4.1.5 Following ingestion:

4.1.6 Self-protection of the Should pay attention to own safety.

first aider:

Do not induce vomiting.

4.1.7 Notes for the doctor:

4.2 Most important symptoms Symptoms: The most important known symptoms and effects are described in the

and effects, both acute and labelling (see section 2) and in section 11. Further symptoms are possible.

delayed

4.3 Indication of any Treatment: Treat according to symptoms (decontamination, vital functions), no

immediate medical attention known specificantidote.

and special treatment needed

5. FIRE-FIGHTING MEASURES

5.1 Extinguishing media:

Suitable

extinguishing Water spray, dry extinguishing media, carbon dioxide, alcohol-resistant foam.

media:

Unsuitable

extinguishing Water jet.

media:

5.2 Special hazards arising from the substance or mixture:

Hazardous

combustion Products of сombustion are carbon oxides and nitrogen oxides, blood poison.

products:

5.3 Advice for fire-fighters:

Wear self-contained breathing apparatus and chemical-protective clothing.

Do not approach to burning containers. Cool the containers with water from the maximum possible distance.

Precipitate the generated gases and vapors with sprayed water.

5.4 Additional information:

Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures:

6.1.1 For non-emergency personnel:

Avoid inhalation. Avoid contact with the skin, eyes and clothing.

Protective equipment:

The wearing of suitable protective equipment (including personal protective

equipment referred to under Section 8 of the SDS) to prevent any contamination of

skin, eyes and personal clothing;

Removal of ignition sources, provision of sufficient ventilation;

Emergency procedures:

the need to evacuate the danger area.

6.1.2 For emergency responders:

Personal protective equipment: Self-contained breathing apparatus and chemical-protective clothing.

6.2. Environmental precautions:

Do not discharge into drains/surface waters/groundwater.

6.3. Methods for cleaning up or taking up:

For large amounts: Pump off product.

For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations.

Do not use saw-dust or other combustible substances as an absorbant during cleanup.

7. HANDLING AND STORAGE

7.1 Precautions for safe handling:

7.1.1 Protective measures:

The product is combustible. Prevent electrostatic charge - sources of ignition

Fire preventions:

should be kept well clear - fire extinguishers should be kept handy.

No smoking.

Ensure thorough ventilation of store and work areas.

Aerosol preventions:

Hermeticity of equipment, product storage tanks, containers.

Environmental precautions:

Page 5 / 10

Safety data sheet according to Regulation EC No № 1907/2006

Date/ revised: 05.09.2013

Product: Monoethanolamine

Version: 3.0 / EN

7.1.2 Advice on general occupational hygiene:

Not to eat, drink and smoke in work areas.

Wash hands after use.

Remove contaminated clothing and protective equipment before entering eating areas.

7.2 Conditions for safe storage, including any incompatibilities:

Avoid extreme heat.

Segregate from acids and acid forming substances.

Keep container tightly closed and in a well-ventilated place.

Keep away from sources of ignition - No smoking.

Storage stability: Storage temperature: 20 °C.

Storage duration: 5-12 Months.

May discolour after lengthy storage.

Data on the storage life specified in the safety data are not a contractual guarantee of the properties of the product.

7.3 Specific end uses:

For a substance designed for a specific end use(s), recommendations attached in the exposure scenarios (exposure

scenarios for identified uses described in Section 1.2 are included of Annex of SDS).

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ensure preliminary and periodic medical examinations

8.1. DNEL/PNEC-values:

DNEL -values:

for workers

1 mg/kg bw/day

3.3 mg/m³

DNEL

for the general population

0.24 mg/kg bw/day

3.75 mg/kg bw/day

2 mg/m³

Exposure

route

Exposure frequency

Dermal

Oral

Inhalation

Long-term - systemic effects

Long-term - systemic effects

Long-term - local effects

Relevant DNELs for the monoethanolamine given in the exposure scenarios of the chemical safety report set out in

the annex to the SDS.

PNEC-values:

Compartments

PNEC

PNEC water

PNEC aqua (freshwater):

PNEC aqua (marine water):

PNEC aqua (intermittent releases):

0.085 mg/L

0.0085 mg/L

0.025 mg/L

PNEC sediment

PNEC sediment (freshwater):

PNEC sediment (marine water):

0.425 mg/kg sediment dw

0.0425 mg/kg sediment dw

PNEC soil

PNEC soil:

0.035 mg/kg soil dw

PNEC sewage treatment plant

PNEC STP:

100 mg/L

Relevant PNECs for the monoethanolamine given in the exposure scenarios of the chemical safety report set out in

the annex to the SDS.

8.2. Exposure controls:

The full range of specific risk management measures to be taken during use in order to minimise worker and

environmental exposure.

8.2.1 Appropriate engineering controls:

Hermeticity of equipment, product storage tanks, containers.

Ensure thorough ventilation of store and work areas.

Avoid extreme heat.

Periodically control the content of harmful substances in the air of the working zone.

Handle in accordance with good industrial hygiene and safety practice.

Page 6 / 10

Safety data sheet according to Regulation EC No № 1907/2006

Date/ revised: 05.09.2013

Product: Monoethanolamine

Version: 3.0 / EN

8.2.2 Personal protective equipment:

8.2.2.1 Eye protection:

Tightly fitting safety goggles (splash goggles) (e.g. EN 166) and face shield.

8.2.2.2 Skin protection:

Hand protection

Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective

index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm),

chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other Manufacturer's directions for use should be observed

because of great diversity of types.

Supplementary note: The specifications are based on literature data and information of glove manufacturers or are

derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the

practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined

through testing.

Body protection:

Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemicalprotection suit (according to EN▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открытьin case of splashes or EN ISO▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открытьin case of dust).

8.2.2.3 Respiratory protection:

Wear respiratory protection if ventilation is inadequate.

Use in case of accidents – filter gas-masks to ensure protection against vapors of organic compounds, e. g. Gas filter

EN▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открытьType A for gases/vapours of organic compounds (boiling point >65 °C).

8.2.2.4 General safety and hygiene measures:

Avoid contact with the skin, eyes and clothing. Do not breathe vapour/spray.

Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required

additionally to the stated personal protection equipment. Take off immediately all contaminated clothing. Store work

clothing separately.

8.2.3 Exposure controls of environmental impact:

Discharge into the environment must be avoided.

To execute the full range of specific RMM and OC required to fulfill commitment under community environmental

legislation.

Adequately control the impact of MEA on the environment is given in the exposure scenarios, annexed to the SDS.

8.2.4 Consumer exposure control:

The product is not intended for use in the home.

Adequately control the impact of MEA on the users is given in the exposure scenarios, annexed to the SDS.

9. PHYSICAL AND CHEMICAL PROPERTIES

Property

Physical state at 20°C and 1013 hPa

Melting / freezing point

Boiling point

Relative density

Vapour pressure

Surface tension

Water solubility

Partition coefficient n-octanol/water (log value)

Flash point

Flammability

Explosive properties

Self-ignition temperature

Results

The substance is an organic, colourless, viscous liquid with

unpleasent, fishy, ammoniacal odour.

10.5 °C

170.3 °C at 1013.25 hPa

1.02 g/cm3 at 20 °C

0.5 hPa at 20 °C

not surface active

> 1000g/l at 20°C (pH 12,1)

-1.91 at 25 °C at pH 7.3

92.5 °C at 1013,25

Non flammable upon ignition.

The substance has no pyrophoric properties and does not

liberate flammable gases on contact with water.

non explosive

410 °C

Page 7 / 10

Safety data sheet according to Regulation EC No № 1907/2006

Date/ revised: 05.09.2013

Product: Monoethanolamine

Version: 3.0 / EN

no oxidising properties

12.1

9.5 at 25 °C

23.18 mPa_s at 20 °C

9.80 mPa_s at 40 °C

Oxidising properties

pH value

Dissociation constant

Viscosity

10. STABILITY AND REACTIVITY

10.1. Reactivity

No hazardous reactions if stored and handled as prescribed/indicated.

10.2. Chemical stability

Monoethanolamine is stable when rules of storage and use are observed.

10.3 Possibility of hazardous reactions:

Reacts with oxidizing agents. The progress of reaction is exothermic. Reacts with acids. Reacts with halogenated

compounds. Reacts with acid chlorides.

10.4 Conditions to avoid:

Avoid extreme temperatures. See MSDS section 7 - Handling and storage.

10.5. Incompatible materials

Substances to avoid: oxidizing agents, isocyanates, acid anhydrides, acid chlorides, acids, acid forming substances,

copper alloys, mild steel.

10.6 Hazardous decomposition products

Carbon oxides and nitrogen oxides.

11. TOXICOLOGICAL INFORMATION

11.1 Toxicokinetics, metabolism and distribution

Topically applied MEA penetrates the skin, is widely distributed and is extensively metabolised in the body. A major

site for metabolism is the liver.

11.2 Information on toxicological effects:

11.2.1 Short-term effects:

Acute toxicity:

Effect dose

Acute oral toxicity

LD 50: 1515 mg/kg bw

Acute dermal toxicity

LD 50: 2504 mg/kg bw

Acute inhalative toxicity

LC 50: 1487 mg/m³ air

Method

Rat

(OECD Guideline 401)

Rabbit

(OECD Guideline 402)

Skin corrosion / irritation:

Skin irritation / corrosion: corrosive.

The European Union (EU) has classified this substance with « Causes burns » (R34).

Serious eye damage/irritation:

Eye irritation: corrosive.

Respiratory or skin sensitisation:

No sensitizing effect.

11.2.3 СMR-effects:

Mutagenicity:

Genetic toxicity: negative.

Carcinogenicity:

MEA is considered to be non-carcinogenic.

Reproductive toxicity

Assessment of teratogenicity:

In animal studies the substance did not cause malformations.

Cat. 3 (H412: Harmful to aquatic life with long lasting effects.)

Route of exposure: inhalative

Specific target organ

toxicity (single exposure)

Remark

Page 8 / 10

Safety data sheet according to Regulation EC No № 1907/2006

Date/ revised: 05.09.2013

Product: Monoethanolamine

Version: 3.0 / EN

12. ECOLOGICAL INFORMATION

12.1. Ecotoxicity:

Longterm-Ecotoxicity:

Long-term effects on

fish

Long-term effects on

aquatic invertebrates

Effect

dose

Exposure

time

Species

Method

NOEC

30 day

Oryzias latipes

NOEC

21 day

Daphnia magna

OECD Guideline

210

OECD Guideline

211

Evaluation

1,2 mg/L

0.85 mg/L

Acute toxicity:

Effect

dose

Acute fish

toxicity

Acute

invertebrates

toxicity

Exposure

time

Species

LC50

96 h

Pimephales promelas

LC50

96 h

Cyprinus carpio

LC50

24 h

24 h

96 h

Carassius auratus

LC50

48 h

Leuciscus idus

melanotus

EC50

48 h

Daphnia magna

Acute algae

toxicity

EC50

72 h

Selenastrum

capricornutum (new

name:

Pseudokirchnerella

subcapitata)

Acute

microorganisms

toxicity

EC10

30 min

Activated sludge

Method

flow-through

flow through laboratory

study according to Geiger

et al.

Directive 92/69/EEC, C.1.

(semi-static)

ASTM method D▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть

(static)

DIN 38412, Part 15

(static)

EU Method C.2 (static)

OECD Guideline 202

Union Carbide Protocol

302 (static)

Evaluation

2070 mg/L test mat.

(nominal)

349 mg/L test

> 5000 mg/L (pH 7)

190 mg/L (pH 10.1)

170 mg/L (pH 10.1)

▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открытьmg/L

65 mg/L

97 mg/L

32.6 mg/L

OECD Guideline 201

2.5 mg/l

OECD Guideline 209

(static)

> 1000 mg/L

Toxicity test results:

With high probability acutely not harmful to fish.

Acutely harmful to aquatic invertebrates.

Acutely toxic for algae.

12.2 Persistence and degradability:

Due to the results of Degradation, the substance is not persistent (not P) and not very persistent (not vP) in the

environment.

The substance is readily biodegradable according to OECD criteria.

Physical- and photo-chemical elimination:

The substance is readily biodegradable. Further, according to structural properties,

Hydrolysis:

hydrolysis is not expected/probable

Phototransformation

After evaporation or exposure to the air, the product will be rapidly degraded by

in air:

photochemical processes

Radily biodegradable.

in water:

Radily biodegradable.

in soil:

Page 9 / 10

Safety data sheet according to Regulation EC No № 1907/2006

Date/ revised: 05.09.2013

Product: Monoethanolamine

Version: 3.0 / EN

Biodegradation in water:

>90 % (DOC removal) (21 d) (OECD Guideline 301 A (new version) (aerobic, activated sludge, domestic).

12.3 Bioaccumulative potential:

Log Kow (Pow): -1.91 at 25 °C.

Because of the n-octanol/water distribution coefficient (log Pow) accumulation in organisms is not to be expected.

Bioaccumulation: the substance is not bioaccumulative (not B) and not very bioaccumulative (not vB).

12.4 Mobility in soil

Assessment transport between environmental compartments:

The substance will not evaporate into the atmosphere from the water surface.

Adsorption to solid soil phase is not expected.

12.5 PBT or vPvB Properties Assessment:

Regarding all available data on biotic and abiotic degradation, bioaccumulation and toxicity it can be stated that the

substance does not fulfil the PBT criteria (not PBT) and not the vPvB criteria (not vPvB).

▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть---Information on: 2-aminoethanol

According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation, Authorisation

and Restriction of Chemicals (REACH): The product does not fulfill the criteria for PBT

(Persistent/bioaccumulative/toxic) and vPvB (very persistent/very bioaccumulative). Self classification.

▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть---Information on: 2,2'-iminodiethanol

According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration, Evaluation, Authorisation

and Restriction of Chemicals (REACH): The product does not fulfill the criteria for PBT

(Persistent/bioaccumulative/toxic) and vPvB (very persistent/very bioaccumulative). Self classification.

12.6 Additional information:

Due to the pH-value of the product, neutralization is generally required before discharging sewage into treatment

plants.

13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Incinerate in suitable incineration plant, observing local authority regulations.

Waste codes / waste designations according to EWC / AVV:

A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the

usage.

The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal

agency/manufacturer/authorities.

Contaminated packaging:

contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being

thoroughly cleaned.

14. TRANSPORT INFORMATION

Land transport

(ADR/RID/GGVSE):

Hazard class: 8.

Packing group: III.

UN number: UN 2491.

Proper shipping name: Ethanolamine.

Hazard label: 8.

Packing group: III.

Sea transport (IMDG - Hazard class: 8.

Marine pollutant: no.

Code/GGVSee):

UN number: UN 2491.

Proper shipping name: Ethanolamine.

Hazard label: 8.

Hazard class: 8.

Packing group: III.

UN number: UN 2491.

Proper shipping name: Ethanolamine.

Hazard label: 8.

Air transport (ICAOIATA/DGR):

Page10/ 10

Safetydatasheetaccordingto RegulationEC No l',M907l2006

Date/revised:05.09.2013

Product:

Monoethanolamine

15. REGULATORY

Version:3.0 / EN

INT'ORMATION

15.1Regulations of the European Union (labeling):

Hazard determining componentfor I abeII ing :

2-AMINOETIIANOL / ETHANOLAMINE

ECNs:▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть

Regulations:

- Directive 67/ 5 49|EEC;

- Regulation(EC) No 1272/2008.

S-phrasesfor monoethanolamine are in accordancewith the Directive 67/548|EEC of June 27,1967 for

harmonizationof legal and administrative regulations on classification, packing and labeling of dangeroussubstances:

S-phrases:

- in caseof contact with eyes,rinse immediately with plenty of water and seekmedical advice;

526

536137/39 - wear suitable protective clothing, gloves and eyelfaceprotection;

- in case of accident or if you feel unwell, seek medical advice immediately (show the lable where

S45

possible).

15.2 Chemical Safety Assessment:

For monoethanolaminehas been carried out a chemical safeWassessment.

16. OTHER INF'ORMATION

16.1 Key sourcefor data: CIBMICAL

SAFETY REPORT.

16.2 Deciphering of the hazard symbols, R-phrases und hazard statements listed in section 3.

Hazard symbols:

- corrosive:

C

Xi

Xn

R-phrases:

▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒▒ - открыть

22

34

38

4l

48t22

-initant;

- harmful.

- harmfulby inhalation,in contactwith skin andif swallowed;

- dangerousif entersthe organism;

- causes

burns;

- causesskin irritation:

- risk of seriousdamageof the eyes;

- dangerousbecauseof the possible serioushealth damagein caseof long-term entering the organism.

Hazard statements:

H332:

Harmful if inhaled.

H3t2.

Harmful in contact with skin.

H314:

Causessevereskin burns and eye damage

H335:

May causerespiratory irritation.

H412:

Harmful to aquatic life with long lasting effects.

H302:

Harmful if swallowed.

H315:

Causesskin irritation.

H318:

Causesseriouseye damage.

H373:

May causedamageto organsthrough prolonged or repeatedexposure.

16.3Applicationto the SDS:

Exposurescenarios

for identifiedusesdescribedin Section1.2 are annexedto the SDS.

I 6.4 Further information:

Vertical lines in the left hand margin indicate an amend

The above information is presented

Standard requirements may be cha

compliancewith the requirementsof stat

Technical director

f'-o 6, ik

1.o1Bj,r=sryr;^)

ton.

rrent knowledge on the material.

of the companies. Providing the

Buyer.